"Twitch Broadcasting Unavailable" - 'Not online'

I've been trying to stream to TwitchTV via the new "ClickToTwitch" but I keep getting this damn error, Twitch Broadcasting Unavailable (You cannot broadcast to Twitch while you are playing offline. Please go online and start Minecraft), every time I try. I've reset my modem/router multiple times, restarted my computer, game and launcher multiple times and I've tracked down to the Launcher Log.
I have included the Launcher Log as a text file attachment, which shows all necessary information. Please give me some suggestions on what to do, as I'm upset that it doesn't work for me.
-Sgarr